1.

Indicate which of the ions may be coloured - V3+, Sc3+, Cr31, Cu2+, Ti3+, Cu+

Answer»
  • V3+[Ar]18 3d2 -(green) Since there are two unpaired electrons available, for d → d transition, it will show a Green colour.
  • Sc3+[Ar]183d° (colourless/white). Since there are no unpaired electrons in the 3d subshell, it will not show colour.
  • Cr3+[Ar]18 3d3 – (violet) There are three unpaired electrons in the 3d subshell, hence due to d → d transition, it will show violet colour.
  • Cu2+[Ar]18 3d9(blue) It has one unpaired electron that can undergo a d → d transition, hence it will show the colour blue
  • Ti3+ [Ar]18 3d1 (purple) It has one unpaired electron that can undergo a d → d transition, hence it will show the colour purple.
  • Cu1+ [Ar]18 3d10(colourless) There are no unpaired electrons in the 3d subshell, hence it will not show colour. 


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