1.

In metal oxide, metal is 33% vapour density of metal chloride is 79 then find out the atomic weight of metal.

Answer»

ANSWER : 13.712 g mol-1

Given : 

Vapour density (VD) of metal chloride = 79

Metal in metal oxide = 33%

To Find : 

Atomic weight of metal = ? 

Solution : 

Let the weight of metal oxide be 100 g.

So the weight of metal will be 33 g and weight of oxygen will be 77.

So equivalent weight (Ew) of metal 

\(= {weight\:of\:metal \over weight\:of\: oxygen } × 8\)

\(={ 33\over77} × 8\)

= 3.428 g

We know that , 

Valency  \(= {2 ×VD\over {E}_{w}+35.5}\)

​​​​\( = {2×79 \over 3.428 + 35.5}\)

\(= {158\over 38.928}\)

= 4.05

≈ 4

Now ,

Atomic weight = valency × Ew 

= 4 × 3.428 

= 13.712 g mol-1

Hence The atomic weight of metal is 13.712 gmol-1



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