1.

In an isothermal process, two soap bubble of radius a and b combine and form a bubble of radius c. If the external pressure is p, then prove that the surface tension of the soap solution is T-(p(c^3-a^3-b^3))/(4(a^2+b^2-c^2)).

Answer»

Solution :We know , the EXCESS pressure inside the soap BUBBLE = internal pressure - external pressure.
`THEREFORE`For the bubble of radius a, excess pressure,
`(4T)/(a)=p_a-p`
`therefore p_a=(p+(4T)/(a))`
Similarly, for the bubble of radius b,
`p_b=(p+(4T)/(b))`
For the bubble of radius c,
`p_c=(p+(4T)/(c ))`
Boyle.s law is applicable in isothermal process. According to this law.
`p_a V_a+p_b V_b=p_c V_c`
or, `(p+(4T)/(a))xx(4)/(3)pia^3+(p+(4T)/(b))xx(4)/(3)pib^3`
`=(p+(4T)/(c ))xx(4)/(3)pic^3`
or, `(p+(4T)/(a))a^3+(p+(4T)/(b))b^3=(p+(4T)/(c ))c^3`
or, `4T(a^2+b^2-c^2)=p(c^3-a^3-b^3)`
`therefore T=(p(c^3-a^3-b^3))/(4(a^2+b^2-c^2))`.


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