1.

In a sample of pitchblende the ratio of ""^(206)Pb, ""^(238)U= 0.2: 1 by weight. If the disintegration constant of ""^(238)U " is " 1.54 xx 10^(-10) per year and all Pb is supposed to be originated from uranium, what will be the age of the mineral?

Answer»

SOLUTION :INITIAL moles: `N^(0)""^(238)U rarr ""^(206)PB`
Moles after time `t: (N^(0)-x) " " x`
`(WT. "of " ""^(206)Pb)/("wt. of" ""^(238)U)= (0.2)/(1)`
`therefore ("mole of" Pb^(206))/("mole of " U^(238))=(0.2//206)/(1//238)= (0.231)/(1)`
or `(x)/(N^(0)-x)= 0.231`
Adding 1 in both sides, `1+ (x)/(N^(0)-x)= 0.231 +1`
`(N^(0))/(N^(0)-x)= 1.231`
We have, `lamda= (2.303)/(t) "log" (N^(0))/(N)`
or `lamda= (2.303)/(t)"log" (N^(0))/(N^(0)-x)`
`1.54 xx 10^(-10) = (2.303)/(t) "log" 1.231`
`t= 1.35 xx 10^(9)` years


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