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If the specific heat capacity of air at constant pressure is 993 J kg ^(-1) K ^(-1)calculate specific heat capacity at constant volume ? Density of air at N.T.P. is 1.293 Kg //m ^(3). [E.Q.)

Answer»

Solution :Specific heat of air at constatn pressure `= C _(p) = 993 j KG ^(-1) K^(-1)`
From the unit of we can SEE that the mass in kg.
So the equation to be used in `C_(p) - C _(V) = r `
`PV = rT, r = (PV)/(T)`
Nrmal temperature `= T = 273 K`
Normal pressure `= P =1` atmosphere `= 101325 Nm ^(-2)`
Volume of air `= V = ?`
Mass of air `= m = 1 kg`
Density of air `= p = 1. 293 kg//m ^(3)`
`thereforeV = (m)/(p) = (1)/(1.293) m ^(3)`
`THEREFORE r = (PV)/(T) = ( 101325)/(273) xx (1)/(1.293) = 287.04 J kg ^(-1) K ^(-1)`
`therefore C _(V) = C _(p) -r = 993 - 287.04 = 705.96JKg ^(-1) K ^(-1)`


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