1.

If the potential energy of a gas molecule is `U=(M)/(r^(6))-(N)/(r^(12)),M ` and `N` being positive constants, then the potential energy at equlibrium must beA. zeroB. `M^(2)//4N`C. `N^(2)//4M`D. `MN^(2)//4`

Answer» Correct Answer - B
Here, `U=(M)/(r^(6))-(N)/(r^(12)),`
`F=-(dU)/(dr)=(-d)/(dr)((M)/(r^(6))-(N)/(r^(12)))`
`=((-6M)/(r^(7))-(12N)/(r^(13)))`
In equilibrium position, `F=0`
`:. (6M)/(r^(7))=(12N)/(r^(13))` or ` r^(6)=(2N)/(r^(13))`
Hence, `U=(M)/((2N//M))-(N)/((2N//M)^(2))=(M^(2))/(4N)`


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