1.

Given compound (A) upon treatment with KMnO4/H+ gives (B), which on heating with ammonia produces (C). (C) on treatment with Br2/NaOH produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of KOH followed by acidification gives (F). (D) is:

Answer»
Given compound (A) upon treatment with KMnO4/H+ gives (B), which on heating with ammonia produces (C). (C) on treatment with Br2/NaOH produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of KOH followed by acidification gives (F).

(D) is:


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