1.

Give reasons(i) Ammonia is a good complexing agent.(ii) In group 15 elements ,the bond angle H-M-H decreases in the following orderNH3(107.8o),PH3 (93.6o), AsH3 (91.8o).

Answer»

(i) Ammonia has a lone pair of electron therefore it is a good complexing agent.

(ii) With the increase in the size of group 15 element as bond length increases the bond pair-bond pair repulsion decreases. Therefore the angle H-M-H decreases from NH3 to AsH3 .



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