1.

For a reaction 2H2O2I−−−−−−−−−−→alkaline medium2H2O+O2 The proposed mechanism is given below: (1) H2O2+I−→H2O+IO−(slow) (2) H2O2+IO−→H2O+I−+O2(fast) (i) Write rate law for the reaction. (ii) Write the overall order of the reaction. (iii) Out of steps (1) and (2), which one is the rate determining step?

Answer» For a reaction
2H2O2I−−−−−−−−alkaline medium2H2O+O2

The proposed mechanism is given below:

(1) H2O2+IH2O+IO(slow)
(2) H2O2+IOH2O+I+O2(fast)

(i) Write rate law for the reaction.
(ii) Write the overall order of the reaction.
(iii) Out of steps (1) and (2), which one is the rate determining step?


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