1.

Find the pH of the following solution:(a) 3.2 g of hydrogen chloride dissolved in 1.00 L of water.(b) 0.28 g of potassium hydroxide dissolved in 1.00 water.

Answer»

(a) Molarity of HCl

\(\frac{3.2}{36.5}\) x 1

0.089 M = 8.9 x 10-2

Since HCl is completely ionized,

[H+] = 8.9 x 10-2 mol L-1

pH = - [log H+]

= -[log 8.9 x 10-2]

= -[-2 + 0.7762] = 1.2238

(b) Molarity of KOH

\(\frac{0.28}{56\times1}\) = \(\frac{1}{200}\) = \(\frac{1}{2\times10^2}\)

= 0.5 x 10-2

= 5 x 10-2 mol l-1

[H+] = \(\frac{K_w}{[OH^-]}\)

[H+] = \(\frac{1.0\times10^{-14}}{5\times10^{-2}}\)

= 0.2 x 10-11

= 2 × 10−12

pH = − log (2 × 10−12)

= −(−12 + 0 ∙ 3010)

= 11.699



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