1.

Explain the structure of graphite giving the reason for its softness as well as its electrical conductivity.

Answer»

Good conductor of electricity: In. graphite carbon atom is sp2 hybridised. Out of four valancy electrons in each carbon atom only three electrons, one from 2s and two from 2p are involved in hybridisation. One spare electron in its 2pz orbital is left free. These 2pz orbital overlap to form delocalised π system which extends above and below each layer. In this delocalised π electrons are free to move within the layer and hence graphite is a good conductor of electricity.

The conductivity of graphite perpendicular to the plane of the layers of hexagons is low and increases with increase in temperature, signifying that graphite is a semiconductor in that direction. The electrical conductivity is much higher parallel to the plane but decreases as the temperature is raised.

Soft, flaky and slippery substance: In graphite each layers of hexagon are held together by a weak Van der Waal’s force of attraction at a large distance of 3.40 Å. Even the slight pressure causes the layers to slide over one another. Hence graphite is soft, flaky and slippery. Graphite is used as a lubricant.



Discussion

No Comment Found