The electronic configuration of 29Cu [Ar] 3d10 4s1 and Cu2+ [Ar] 3d9.
In copper compounds Cu2+ ions have incompletely filled 3d-orbital (3d9).
Due to the presence of one unpaired electron in 3 d-orbital, Cu2+ ions absorb red light from visible spectrum and emit blue radiation due to d → d transition. Therefore, copper compounds are coloured.