1.

Explain preparation of hydrogen using electrolysis.

Answer»

High purity of hydrogen (>99.9%) is obtained by the electrolysis of water containing traces of acid or alkali or electrolysis of aqueous solution of sodium hydroxide or potassium hydroxide using a nickel anode and iron cathode. This process is not economical for large scale production.

At anode : 2OH- → H2O + \(\frac{1}{2}\)O2 + 2e- 

At cathode : 2H2O + 2e- → 2OH- + H2 

Overall reaction : H2O → H2 + 14 O2



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