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Draw main conformation of n-butane obtained by rotation around C-2 and C-3 also give the names of these conformations. Which of these conformation is most and which is the least stable and why? |
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Answer» anes increase, the conformation possibilities also increases. The lowest energy CONFIGURATION, called the anti-periplanar (or anti)configuration, is the one in which the two large methyl groups are as far apart as possible. When ROTATION occurs around the C(2)-C(3) bond, another eclipsed (anti-clinical) conformation is achieved in which two Me-H interactions and one H-H INTERACTION OCCUR. The syn-periplanar configuration is less stable whereas the anti-periplanar configuration is more stable." |
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