1.

Derive and explain Acid Catalyzed Ring Opening

Answer»

Titanium and ZIRCONIUM COMPLEXES of bispicolinic amides CATALYZE the ring opening of CYCLOHEXENE oxide with trimethylsilyl azide as nucleophile. The product, 1-azido-2-trimethylsilyloxycyclohexane, was obtained in up to 71% enantioselectivity when a catalyst



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