1.

Consider the cell Ag(s)|AgBr(s)||Br−(aq)||AgCl(s)|Cl−(aq)|Ag(s)25∘C.The solubility product constants of AgBr and AgCl are respectively 5×10−13 and 1×10−10. For what ratio of the concentration of Br− and Cl− ions would the emf of the cell be zero?

Answer» Consider the cell
Ag(s)|AgBr(s)||Br(aq)||AgCl(s)|Cl(aq)|Ag(s)25C.The solubility product constants of AgBr and AgCl are respectively 5×1013 and 1×1010. For what ratio of the concentration of Br and Cl ions would the emf of the cell be zero?


Discussion

No Comment Found