1.

Comment on the extent to which the forward reaction will proceed, from the magnitude of the equilibrium constant for the following reactions :i. H2(g) + I2(g) ⇌ 2HI(g), KC = 20 at 550 Kii. H2(g) + Cl2(g) ⇌ 2HCl(g), KC= 1018 at 550 K

Answer»

i. H2(g) + I2(g) ⇌ 2HI(g), KC = 20 at 550 K

For the reaction, 

KC = 20 at 550 K 

If the value of KC is the range of 10-3 to 103,

The forward and reverse proceed to equal extents.

Hence,

The given reaction will form appreciable concentrations of both reactants and the product at equilibrium.

ii. H2(g) + Cl2(g) ⇌ 2HCl(g), KC= 1018 at 550 K

For the reaction,

KC= 1018 at 550 K

If the value of KC >>> 103, forward reaction is favoured.

Hence,

The given reaction will proceed in the forward direction and will nearly go to completion.



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