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Cis-dichlorobis(2,2-bipyridine)ruthenium(ii) preparation procedure

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Answer:

A new synthesis of cis-[Ru(bipy)2Cl2] is presented STARTING from [Ru(bipy)py4]2+. Also, a method for OBTAINING cis-TRANS mixtures of [Ru(bipy)2Cl2] is described. During conversion of trans[Ru(bipy)2py2]2+ to [Ru(bipy)2Cl2] ISOMERIZATION is found to occur.

Explanation:



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