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(CH3)3C−CH=CH2(A)HCl−−→B+C (Both of molecular formula C6H13Cl) Balc. KOH−−−−−−→△D (an isomer of A) Ct−Bu−ONa−−−−−−−→△A DO3/H2O−−−−−→ZnE (This gives negative test with Fehling Solution but responds to iodoform test) AO3/H2O−−−−−→Me2SF+G (Both give positive Tollens test but do not give iodoform test) F+Gconc NaOH−−−−−−−→HCOONa+H (a primary alcohol) Gconc NaOH−−−−−−−→H+J H1. conc H2SO4/△−−−−−−−−−−→2. O3/H2O/ZnE+K List-I contains questions related to reaction sequences given above and List-II contains their answers. List - IList - II(I)Which compound(s) can perform cannizzaro(P) Kreaction but not Aldol condensation reaction?(II) Which compound(s) when heated with conc(Q) AH2SO4 give(s) mesitylene?(III) Which compound(s) performed rearrangement(R) Gof 1,2-methyl shift during reaction?(IV) Which compound(s) can perform Aldol(S) Hcondensation reaction but no Cannizzaro reactionwhen treated with dilute NaOH?(T) E(U) F Which of the following options has the correct combination considering Lists-I and II? |
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Answer» (CH3)3C−CH=CH2(A)HCl−−→B+C (Both of molecular formula C6H13Cl) Balc. KOH−−−−−−→△D (an isomer of A) Ct−Bu−ONa−−−−−−−→△A DO3/H2O−−−−−→ZnE (This gives negative test with Fehling Solution but responds to iodoform test) AO3/H2O−−−−−→Me2SF+G (Both give positive Tollens test but do not give iodoform test) F+Gconc NaOH−−−−−−−→HCOONa+H (a primary alcohol) Gconc NaOH−−−−−−−→H+J H1. conc H2SO4/△−−−−−−−−−−→2. O3/H2O/ZnE+K List-I contains questions related to reaction sequences given above and List-II contains their answers. List - IList - II(I)Which compound(s) can perform cannizzaro(P) Kreaction but not Aldol condensation reaction?(II) Which compound(s) when heated with conc(Q) AH2SO4 give(s) mesitylene?(III) Which compound(s) performed rearrangement(R) Gof 1,2-methyl shift during reaction?(IV) Which compound(s) can perform Aldol(S) Hcondensation reaction but no Cannizzaro reactionwhen treated with dilute NaOH?(T) E(U) F Which of the following options has the correct combination considering Lists-I and II? |
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