1.

Cell voltages and half-cell potentials are often compeared under standard conditions called the standard state at a specified temperature (298K). The standard state requires all reagents to be pure with all gases at unit fugacity, all ions at unit activity and all electrical connections between half-cells to be made with platinum. Suppose following are half cell reaction, with respective emf (s) are -0.25 V and -0.3V. Cell reaction I underset("1 atm")(Pt(H_(2))|HCl) Cell reaction II underset("1 atm")(Pt(H_(2))|H_(2)SO_(4)) pH value of cell reaction I is

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4.23
5.23
5.08
5.32

Answer :A


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