1.

Cations are classified into varius groupon the basis oftheir behaviour againstsomereagents .The groupreagentused for the classifactionof most common cationare HCI,H_(2)S,NH_(4)OH,(NH_(4))_(2)CO_(3). Classification is based on whether a cationreacts withthese reagents by theformationof precipitates ornot .An aqucous solution which is sightly acids contains cattions Fe^(2+),Zn^(2+) and Cu^(2+). THe rengent added in excess to this solutionwould identify the separate Fe^(2+) ion in one step is

Answer»

`2M HCI`
`6M NH_(3)`
`6M NaOH`
`H_(2)S gas `

Solution :`Fe^(3+) + 3NH_(4)OH rarr Fe(OH)_(3) darr ("reddish brown") +3NH_(4)^(o+)`
`Cu^(2+) + 4NH_(3) rarr underset(("blue COLOUR soluble complex"))([Cu(NH_(3))_(4)]^(2+))`
` Zn^(2+) + 4NH_(3) rarr underset(("colourless soluble complex"))([Zn(NH_(3))_(4)]^(2+))`


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