1.

Calculatethe freezingpoint of theone molaraqueoussolution(density 1.04 gL^(-1)) of KCl (k_(f) for wateer= 1.86 kg mol^(-1) , atomic mass of K = 39 ,Cl = 35.5)

Answer»


Solution :1 molarsolutionmeansthat 1 MOLE of KCI is dissolvedin 1000 ML of solution.
Mass of solution` = 1000xx 1.04 = 1040 g`
Mass of KCl= 74.5 g
Mass of water= 1040-74.5 = 965.5 g .
MOLALITYOF solution`= (1)/(965.5) XX 1000 = 1.0357` m
SINCE KCl is strongelectrolyte, i = 2
`Delta T_(f) =i K_(f) xx m`
`= 2 xx 1.86 xx 1.0357 = 3.852^(@)`
Freezingpointof solution ` = 0 - 3.852 = - 3.852^(@)C`


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