1.

Calculatepackingefficinecy in thecrystal of body -centredcubic (bcc) structure.

Answer»

Solution :Body -centred cubic (bcc) structure: In thisunit cell, THEREARE 8 atoms at 8 cornersand one atom atthe body centre .
`therefore` Total NUMBER of atoms `= 8 xx (1)/(8) + 1 = 1 + 1 = 2`
If a is the edgelengthof cubicunit cell and r is theradius of an atom them, in bcc unitcell `r =(sqrt(3))/(4) xxa`
VOLUMEOF unit cell `=a^(3) = ((4)/(sqrt(3))xx r)^(3) = (64)/(3sqrt(3))r^(3)`
Volumeof 1 atom `= (4)/(3)pir^(3)`
`therefore` Packing fraction `=("Volumeoccupiedby 2atoms")/("Volume of unit cell")`
`=(2xx(4)/(5)pir^(3))/((64)/(3sqrt(3))r^(3))`
`= (sqrt(3)pi)/(8)`
`=(sqrt(3) xx 3.142 )/(8)`
` = 0.68`
`therefore` Packingefficinecy `= 0.68 xx 10= 68%`
`therefore` %of voidspace= 100-68 = 32% .


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