1.

Calculate the rms speed in cm/s at 25^(@)C at a free electron and of a molecule of UF_(6). (H = 1 , U = 238, F = 19)

Answer»

Solution :Mass of electron on atomic wt. scale is 1/1837 amu
`THEREFORE` mass of 1 mole of electron `= (1)/(1837)g`.
`R = 8.314 xx 10^(7)` ergs/k/mole
`T = 273 + 25 = 298 K`.
We have,
`C = sqrt((3RT)/(M)) = sqrt((3 xx 8.314 xx 10^(7) xx 298)/(1//1837))`
`therefore` rms speed of an electrons `1.16 xx 10^(7)` cm/s.
To calculate rms spd. of `UF_(6)`, put `M = (238 + 6 xx 19)`


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