1.

Calculate the packing efficiency in simple cubic unit cell.

Answer»

SOLUTION :In a simple cubic UNIT cell, two spheres at the corners of the cube touch each other.
Let edge length of cube = a.
Let radius of SPHERE = R
The radius of sphere and edge length of cube is related as:
a = 2r
The volume of cubic unit cell `= a^3 = (2r)^3 = 8r^3`
Since the simple cubic unit cell contains only 1 atom, the volume of the occupied space is= `4/3 pi r^3`
% Packing efficiency =`("Volume occupied by four spheres in unit cell" xx 100)/("Volume of the unit cell")`
` = 4/3 pi r^3_(8 r^3) xx 100 = pi/6 xx 100`
`52.4%`.


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