1.

Calculate the lattice enthalpy of CaCl2 , given that : Enthalpy of sublimation for Ca(s) → Ca(g) = 121 kJ mol−1 Enthalpy of dissociation of Cl2(g) → 2Cl(g) =242.8 kJ mol−1 Ionisation energy of Ca(g)→ Ca++(g) =2422 kJ mol−1 Electron gain enthalpy of 2Cl→ 2Cl−1=(2×−355) kJ mol−1=−710 kJ mol−1 Enthalpy of formation of CaCl2=−795 kJ mol−1

Answer»

Calculate the lattice enthalpy of CaCl2 , given that :
Enthalpy of sublimation for Ca(s) Ca(g) = 121 kJ mol1
Enthalpy of dissociation of Cl2(g) 2Cl(g) =242.8 kJ mol1
Ionisation energy of
Ca(g) Ca++(g) =2422 kJ mol1
Electron gain enthalpy of 2Cl 2Cl1=(2×355) kJ mol1=710 kJ mol1
Enthalpy of formation of CaCl2=795 kJ mol1



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