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Calculate the first dissociation constant of H_(3)PO_(4) if the e.m.f. of the cell, Hg|Hg_(2)Cl_(2)(s)|KCl("salt")(conc.=4N)||H_(3)PO_(4)(0.1M)|H_(2)(1atm)|Pt,-0.3665V.E_(red)^(@) of SCE=0.2412V.(10^(-212)=131.82) |
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