1.

Calculate the concentration of f- in a solution saturated with mgf2 and srf2. Given ksp of mgf2 is 9.5*10-9 and ksp of srf2 is 4*10-9

Answer»

[F^-]=1.59\times 10^{-4}mol./LAnswer: TOTAL  CONCENTRATION of FLUORINE IONS

Explanation:

1) MgF_2\rightleftharpoons Mg^{2+}+2F^-

         S                2S

K_{sp}  of MgF_2 = 9.5\times 10^{-9}=[S][2S]^2=4S^2

S=4.87\times 10^{-5} mol/L

Concentration of fluorine ions in saturated SOLUTION of MgF_2

[F^-]_{MgF_2}=2S=2\times 4.87\times 10^{-5} mol/L=9.74\times 10^{-5}mol/L...(1)

2) SrF_2\rightleftharpoons Sr^{2+}+2F^-

             S'                2S'

K_{sp} of SrF_2 = 4\times 10^{-9}=[S'][2S']^2=4S'^2

S'=3.1\times 10^{-5}mol/L

Concentration of fluorine ions in saturated solution of SrF_2

[F^-]_{SrF_2}=2S=2\times 3.1\times 10^{-5} mol/L=6.2\times 10^{-5}mol/L...(2)

[F^-]Total  Concentration of fluorine ions

=[F^-]_{MgF_2}+[F^-]_{SrF_2}=9.74\times 10^{-5}mol/L+6.2\times 10^{-5}mol/L=15.94\times 10^{-5}mol/L=1.59\times 10^{-4}mol./L




Discussion

No Comment Found