1.

Calculate the buffer capacity of `1L` solution of : `(i)0.1MCH_(3)COOH` and `0.1MCH_(3)COONa` `(ii) 0.2MCH_(3)COOH` and `0.2MCH_(3)COONa` Given:`pK_(a)(CH_(3)COOH)=4.74` Which will be a better buffer?

Answer» Buffer capcaity =`(2.303(a+x)(b-x))/(a+b)~~(2.303ab)/(a+b)xltlta,b`
Buffer capacity =`(0.1xx0.1xx2.303)/(0.1+0.1)=0.11515`
Buffer capacity `=(0.2xx0.2xx2.303)/(0.2+0.2)=0.2303`
Second buffer solution (having greater buffer capcity )can be called butter buffer.


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