1.

Benzamide (A) is prepared by heating benzoic acid with ammonia. It undergoes the following reactions: A underset("reaction 1")overset(Br_(2),KOH, Delta)(to) B underset(273-278K "reaction 2")overset(NaNO_(2),HCl)(to) C underset(Delta "reaction 3")overset(H_(3)PO_(2),H_(2)O)(to) D underset(anhyd AlCl_(3) "reaction 4")overset(CH_(3)Cl)(to) E E on heating with acidic KMnO_(4) gives back benzoic acid. 3. Write the chemical reaction for reaction 2 if temperature is 298K.

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