1.

At times warming is suggested while precipitating group V cation explain.

Answer»

Solution :The IMPURITY of bicarbonate ion in `(NH_(4))_(2)CO_(3)` fomrs decomposes these bircarbonates into normal carbonates which are precipitated
`Ca(HNO_(3))_(2)toCaCO_(3)+H_(2)O+CO_(2)`
the solution MUST not be boiled otherwise insoluble carbonates with ammonium chloride are converted into soluble chlorides.


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