1.

At equilibrium N2o4=2no2 the observed molecular weight of n2o4 is 80 g at 350 k the %of dissociation of n2o4(g) at350 k is

Answer»

N_2O_5Answer: Percentage dissociation of for the given reaction is 15%.

Explanation: We are given a chemical EQUATION:

               N_2O_4\rightleftharpoons 2NO_2

at t = 0           1           0

at t=t_{eq}    1-\alpha        2\alpha

Normal molecular mass of N_2O_5 = 92 g/mol

Observed molecular mass of N_2O_5 = 80 g/mol

Van't Hoff FACTOR for dissociation is given by:

i=\frac{\text{Normal Molecular mass}}{\text{Observed Molecular mass}}

For ASSOCIATION, i < 1

For dissociation, i > 1

Putting values in above equation, we get:

i=\frac{92}{80}=1.15

Expression for Van't Hoff equation is given by:

i=\frac{\text{Observed colligative property}}{\text{Calculated colligative property}}

i=\frac{1-\alpha +2\alpha }{1}

i=\frac{1+\alpha }{1}

where,

i = Van't Hoff factor

\alpha = DEGREE of dissociation or association.

1.15=1-\alpha \\\alpha = 0.15

N_2O_4Percentage of dissociation for is given by:

\text{Percentage dissociation of }N_2O_4=\alpha \times 100=0.15\times 100=15\%



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