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At a certain temperature the following equilibrium is established CO(g)+NO_2(g)hArrCO_2(g)+NO(g) One mole of each of the four gas is mixed in one litre container and the reaction is allowed to reach equilibriumstate.When excess of baryta water (Ba(OH)_2) is added to the equilibrium mixture, the weight of white ppt. (BaCO_3) obtained is 236.4 gm.The equilibrium constant K_C of the reaction is (Ba=137) |
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Answer» 1.2 `CO_2+Ba(OH)_2 to BaCO_3` mole of `BaCO_3=263.4/197=1.2` So mole of `CO_2` at eq. =12 or 1+x=1.2 x=0.2 `K_C=((1+x)/(1-x))^2=((1.2)/(0.8))^2 =2.25` |
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