1.

At 25^(@) the specific conductance of a saturated solution of AgCl after subtracting the specific conducatnce of water is 1.82 xx 10^(4) Sm^(-1). The molar conductance at infinite dilution of AgNO_(3), HNO_(3) and HCl are respectively 133.0 xx 10^(-4), 421.0 xx 10^(-4) and 426 xx 10^(-4) S m^(2) "mol"^(-1). Find the solubility of AgCl. Write down the half cell reaction and calculate standard reduction potential for that the half Pt | 50mL 0.5 M KCl solution in which few drops of 0.1 M E_(Ag, Ag)^(0)=0.80V.

Answer»


Answer :`1.32 xx 10^(-5)" MOL dm"^(-3)`
0.224 V
Half cell REACTIONS
`AgCl(s)+e^(-) to Ag(s)+Cl^(-) (aq)`


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