1.

At 25^(@)C , the activation energies for a reaction in absence and presence of a catalyst areE_(a) and (E_(a) -2) "kcal.mol"^(-1) , respectively . For the reaction , the reaction -rate and enthalpy change in absence of catalyst are r "mol.L"^(-1).s^(-1) and DeltaHk "cal.mol"^(-1) , respectively . which of the following would be true regarding the reaction when it is carried out in presence of a catalyst -

Answer»

reaction -rate`= 14xxr "mol"^(-1).L.s^(-1)`
reaction -rate`= 28xxr "mol"^(-1).L.s^(-1)`
change in enthalpy`= DELTAH "kcal.mol"^(-1)`
change in enthalpy `=(DeltaH)/(2)"kcal.mol"^(-1)`

Answer :B::C


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