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Assuming the compounds to be completely dissociated in aqueous solution, identify the pair of the soltions which can be expected to be isotonic at the same temperature ? |
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Answer» `0.01 M " urea and " 0.01 M NaCI` For isotionic solution, `pi_(1)=pi_(2)` Sincethe two sloutions are at the same temperature, `i_(1)C_(1)RT=i_(2)C_(2)RT` (a) For urea, `i_(1)=1, C_(1)=0.01M` `"For" NaCI, i_(2)=2, C_(2)=0.01M` `1xx0.01xxRT ne2xx0.01xxRT ("Not isotonic") ` (b)`" For" Naci, i_(1)=2,C_(1)-0.02M` For `Na_(2)SO_(4), i_(2)=3, C_(2)=0.01 M` `2xx0.02xxRTnr3xx0.01xxRT` ("Not isotonic")` (c) For NaCI, `i_(1)=2, C_(1)=0.03 M` For `MgCI_(2), i_(2)=3,C_(2)=0.02 M` `2xx0.03 xxRT=3xx002xxRT` (d) For SUCROSE, `i_(1)=1, C_(1)=0.01M` For glucose, `i_(2)=1,C_(2)=0.02M` `1xx0.01xxRT =2xx0.02xxRT` (Not isotonic) is the correct answer. |
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