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Assertion: I Daniell cell, if concentrations of Cu^(2+) ions and Zn^(2+) ions are doubled, emf of the cell will be doubled. Reason: If concentration of ions in contact with the metal is doubled, the electrode potential is doubled. |
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Answer» If both assertion and reason are true, and reason is the true explanation of the assertion Thus, if `[Zn^(2+)]` and `[Cu^(2+)]` are DOUBLED, there is no effect of emf. Correct R. `Cu^(2+)+2e^(-)toCu,E=E^(@)-(RT)/(nF)"ln"(1)/([Cu^(2+)])` Thus, if `[C^(2+)]` is doubled, E is not doubled. |
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