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Assertion (A): In 3d transition elements, the expected decrease in atomic radius is observed from Sc to V, thereafter upto Cu, the atomic radius nearly remains the same. Reason (R): As we move from Sc to V, the added 3d electrons only partially shield the increased nuclear charge but upto Cu, the extra electron added to 3d sub-shell repel the 4s electrons and the slight increase in nuclear charge operated in opposite direction and it leads to constancy in atomic radii. |
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Answer» Both (A) and (R) are CORRECT and (R) EXPLAINS (A). |
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