1.

Assertion: 1-butene on reaction with HBr in the presence of a peroxide produces 1-bromobutane. Reason:It involves the formation of a primary radical

Answer»

Both assertion and reason are correct and reason is the correct explanation of the assertion
Both assertion and reason are correct but reason is notthe correct explanation of the assertion
Assertion is correct, but reason is incorrect
Assertion is incorrect, but reason is correct

Solution :Assertion is correct but reason is incorrect because 1-butene on reaction with HBr in the presence of a PEROXIDE produces 1-bromobutene. In this reaction, secondary free radical is formed as INTERMEDIATE PRODUCT.
(i)(a)`(C_6H_5CO)_2 O_2 to 2C_6H_5COO^(.)`
(b)`C_6H_5COO^(-)+HBr to C_6H_5COOH +Br^(.)`
(II)`CH_3-CH_2-CH=CH_2+Br^(.)to CH_3-CH_2-Coverset(dot)H-CH_2Br`
(iii)`CH_3-CH_2-overset(dot)CH-CH_2Br + H -Br to CH_3-CH_2 -CH_2 -CH_2Br+Br^(dot)`


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