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Arrange the following sulphates of alkaline earth metals in order of decreasing thermal stability: `BeSO_(4),MgSO_(4),CaSO_(4),SrSO_(4)`. |
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Answer» Sulphate decompose on heating to give the corresponding oxide. `MgSO_(4)overset(Delta)(rarr)MgO+SO_(2)+(1)/(2)O_(2)` The stability increases as the electropositive character of the metal or basic nature of the metal increases down the group `(darr)`. This is clear form the increasing decomposition temperature down the group. `1647 K 1422 K 1168 K773 Krarr` Temperature of decomposition `SrSO_(4) gt CaSO_(4) gt MgSO_(4) gt BeSO_(4)` |
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