1.

Arrange the following in order of increasing boiling point: (i) CH_(3)CH_(2)CH_(2)CH_(2)Br (ii) (CH_(3))_(3)CB r (iii) (CH_(3))_(2)CHCH_(2)Br.

Answer»

Solution :The b.p. increases as the BRANCHING decreases (or the SURFACE AREA increases), i.e., `(CH_(3))_(3)CB R lt (CH_(3))_(2)CHCH_(2)Br lt CH_(3)CH_(2)CH_(2)CH_(2)Br`.


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