1.

Arrange the elements of second period in order of increasing second ionization enthalpies.

Answer»

The electronic configuration of the ions obtained after removal of first electron from the elements of 2nd period from left to right are: Li+ (1s2), Be+ (1s2 2s1), B+ (1s2 2s2), O (1s2 2s2 2p1), N+ (1s2 2s2 2p2), O- (1s2 2s2 2p3), F (1s2 2s2 2p4), Ne+ (1s2 2s2 2p3). 

The following conclusions can be drawn from the above configurations: 

(i) Li+ has noble gas, i.e., He gas configuration, therefore, AlH2 of Li is the highest in the second period. 

(ii) Since in B+, the electron has to be removed from a more stable fully filled 28- orbital while in Be+, it has to be lost from the less stable half-filled 2s-orbital and furthermore, the loss of an electron from Be+ gives more stable Be2+ ion with noble gas configuration, therefore, AjH2 of Be is lower than that of B.

(iii) Since more energy is required to remove an s-electron than a p-electron of the same energy level, therefore, more energy is required to remove a 2s-electron from B+ (1s2 2s2) than a 2p-electron from C+ (1s2 2s2 2P1). In other words, ΔiH2 of C is lower than that of B. 

(iv) As we move from C to N to O, the nuclear charge increases by one unit at a time, therefore, their ΔiH2 also increase accordingly. In other words, ΔiH2 of O is higher than that of N which, in turn, is higher than that of C. 

(v) In case of O+ (1s2 2s2 2p3) an electron is to be lost from an exactly half-filled 2p-orbital but in case of F+( 1s2 2s2 2p4) this is not so. However, loss of an electron from F+ gives an exactly half-filled 2p-orbital (i.e., F2+ ( 1s2 2s2 2p3), therefore, ΔiH2 of F should be lower than that of O. 

(vi) Like O+ (1s2 2s2 2p3) and F+ (1s2 2s2 2p4), in case of Ne+ (1s2 2s2 2p5) also an electron is to be removed from a 2p-orbital. Since Ne has the highest nuclear charge in 2nd period, ΔiH2 of Ne is expected to be much higher than that of O or F. From the above discussion, it follows that ΔiH2 of the elements of 2nd period increase in the order: Be < C < B < N < F < O < Ne < Li.



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