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Arrange the elements of second period in order of increasing second ionization enthalpies. |
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Answer» The electronic configuration of the ions obtained after removal of first electron from the elements of 2nd period from left to right are: Li+ (1s2), Be+ (1s2 2s1), B+ (1s2 2s2), O (1s2 2s2 2p1), N+ (1s2 2s2 2p2), O- (1s2 2s2 2p3), F (1s2 2s2 2p4), Ne+ (1s2 2s2 2p3). The following conclusions can be drawn from the above configurations: (i) Li+ has noble gas, i.e., He gas configuration, therefore, AlH2 of Li is the highest in the second period. (ii) Since in B+, the electron has to be removed from a more stable fully filled 28- orbital while in Be+, it has to be lost from the less stable half-filled 2s-orbital and furthermore, the loss of an electron from Be+ gives more stable Be2+ ion with noble gas configuration, therefore, AjH2 of Be is lower than that of B. (iii) Since more energy is required to remove an s-electron than a p-electron of the same energy level, therefore, more energy is required to remove a 2s-electron from B+ (1s2 2s2) than a 2p-electron from C+ (1s2 2s2 2P1). In other words, ΔiH2 of C is lower than that of B. (iv) As we move from C to N to O, the nuclear charge increases by one unit at a time, therefore, their ΔiH2 also increase accordingly. In other words, ΔiH2 of O is higher than that of N which, in turn, is higher than that of C. (v) In case of O+ (1s2 2s2 2p3) an electron is to be lost from an exactly half-filled 2p-orbital but in case of F+( 1s2 2s2 2p4) this is not so. However, loss of an electron from F+ gives an exactly half-filled 2p-orbital (i.e., F2+ ( 1s2 2s2 2p3), therefore, ΔiH2 of F should be lower than that of O. (vi) Like O+ (1s2 2s2 2p3) and F+ (1s2 2s2 2p4), in case of Ne+ (1s2 2s2 2p5) also an electron is to be removed from a 2p-orbital. Since Ne has the highest nuclear charge in 2nd period, ΔiH2 of Ne is expected to be much higher than that of O or F. From the above discussion, it follows that ΔiH2 of the elements of 2nd period increase in the order: Be < C < B < N < F < O < Ne < Li. |
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