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Aromatic primary amines are not prepared by gabriel phthalimide synthesis

Answer»

Answer:

✔Aromatic amines cannot be prepared by Gabriel Phthalimide synthesis reaction because aryl halides do not undergo nucleophilic SUBSTITUTION with the ANION formed by phthalimide.

✔It is USED for the preparation of primary aliphatic amines.

✔Phthalimide on treatment with ethanolic POTASSIUM hydroxide forms potassium salt of phthalimide which on heating with alkyl halide followed by ALKALINE hydrolysis produces the corresponding primary amine.



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