1.

Aqueous solution of a salt 'A', when mixed with NaoH solution and warmed, a black precipitate is formed. Black ppt. is filtered and dissolved in dil. H_(2)SO_(4) solution. The resulting solution gives a chocolate coloured precipitate with potassium ferrocyanide solution. the filtrate obtained after filtering off the black precipitate, upon warming with Zn and NaOH evolves a pungent smelling gas. the resulting solution also responds to the ring test. the filtrate does not evolve any gas when it is boiled with urea in the presence of H_(2)SO_(4). Q. Salt 'A' consists of:

Answer»

`Cu^(2+)`
`HG^(2+)` SALT
`Cu^(+)`
`Pb^(2+)`

SOLUTION :


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