1.

An unknown mixture contains one or two of the following: CaCO_(3),BaCl_(2),AgNO_(3),Na_(2)SO_(4),ZnSO_(4) and NaOH. The mixture is completely soluble in water and solution gives pink colour with phenolphthalein. When dilute hydrochloric acid is gradually added to the solution, a precipitate is formed which dissolved with further addition of the acid. Q. The aqueous solution of mixture gives white precipitate with dil. HCl which dissolves in excess of dil HCl . it confirms.

Answer»

`BaCl_(2)+NaOH`
`Na_(2)SO_(4)+NaOH`
`ZnSO_(4)+NaOH`
`AgNO_(3)+NaOH`

Solution :Mixture contains `NaOH+ZnSO_(4)`
`NaOH+ZnSO_(4) to underset("SOLUBLE")(Na_(2)ZnO_(2))+Na_(2)SO_(4)+2H_(2)O`
`Na_(2)ZnO_(2)+2HCl to 2NaCl+Zn(OH)_(2)darr`
`Zn(OH)_(2)+2HCl to underset("soluble")(ZnCl_(2))+2H_(2)O`


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