1.

An prgamoc cp,[pimd C_(5)H_(9)Br(A) which readily decolourises bromine water and cold alkaline KMnO_(4) solution gives C_(5)H_(11)Br(B) on catalytic hydrogenation. The reaction of A with alcoholic KOH first and then with NaNH_(2) produces C with evolution of NH_(3). C reacts with Lindlar's catalyst to give D and on reaction with Na in liquid NH_(3) produces E. D and E are isomers. The compound A is

Answer»

`CH_(3)CH_(2)CH=OVERSET(BR)overset(|)C-CH_(3)`
`CH_(3)CH_(2)-overset(Br)overset(|)C=CHCH_(3)`
Both (a) and (b)
Neither (a) nor (b)

SOLUTION :


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