1.

An organic compound containing C, H and O gives following observations: (i) It exists in two isomeric forms (A) and (B). (ii) 0.108 g of one of the isomers on combustion gave 0.308 g of CO_(2) and 0.072 g of H_(2)O (ii) 0.108 g of one of the isomers on combustion gave 0.308 g of CO_(2) and 0.072 g of H_(2)O (iii) (A) is insoluble in NaOH and NaHCO_(3) while (B) is soluble in NaOH. (iv) (A) reacts with Hl to give compound (C ) and (D). (C ) can be separated from (D) by ethanolic AgNO_(3) solution and (D) is soluble in NaOH. (v) (B) readily reacts with bromine water to give compound (E) of molecular formula C_(7)H_(5)OBr_(3) Compound (C)overset("Moist"Ag_(2)O)rarr(P)underset(CH_(2)Cl_(2))overset(PC C)rarr(Q) The product (Q) is

Answer»

FORMALDEHYDE
formic ACID
ETHANOIC acid
acrylic acid

ANSWER :A


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