1.

An organic compound A containing C = 70% and H =11.6% gave the following results : (P) 0.384 gm of the compound A displaced 100 ml of air at 1 atm and 273 K. (Q) On treatment with PCl_(3)A gave another compound, which contained 33.97%(34%)chlorine. An ismor of it B gave compound C containing 50.35% chlorine with PCl_(5).C gives back B with aq. KOH correct structure of B is:

Answer»

pent-4-en-1-ol
cyclopentanone
1,3-epoxypentane
3-pentanone

Solution :`{:(""O),(""||),(CH_(3)-CH_(2)-C-CH_(2)CH_(3)),(""downarrowPCl_(5)),(""CL),(""|),(CH_(2)-CH_(2)-C-CH_(2)-CH_(3)(50.33%Cl)),(""|),(""Cl):}`


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