1.

An organic compound 'A' (C_(16)H_(13)O_(2)N) is insoluble in dil cold aqueous alkali but on warming gives a clear solution. ‘A’ when treated with dil H_(2)SO_(4) gives B(C_(16)H_(15)O_(2)N) which when boiled with conc. HCl under reflux and cooled, a solid compound C(C_(8)H_(6)O_(4)) is crystallized out. The mother liquor when separated and concentrated gives D(C_(8)H_(12)NCl). Compound ‘D' can be

Answer»

`Ph(CH_(2))_(2)NH_(3)^(+)CL^(-)`
`PhCH(CH_(3))NH_(3)^(+)Cl^(-)`
`Ph.NH^(+)(CH_(3))_(2)Cl^(-)`
Both (a) and (b)

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