1.

An organic (A) reacts with PCl_(5)to produce another compound (B). (B) reacts with magnesium metal in presence of ether to produce a Grignard reagent (C). (C) reacts with ethanal and the3 product is hydrolysed to produce propan-2-ol. Identify (A), (B) and (C) and explaiin the reactions.

Answer»

Solution :(i) Since prop-2-ol is OBTAINED by the action of a grignard reagent (C) on ethanal followed by hydrolysis, therefore, grignard reagent (C) must be `CH_(3)MgCl`
`underset("Methylmagg. Chloride")(CH_(3)MgCl)+underset("Ethanal")(CH_(3)CHO) to [CH_(3)-overset(OMgBr)overset(|)(C)H-CH_(3)]overset(H^(+)//H_(2)O)to underset("Propan-2-ol")(CH_(3)-overset(OH)overset(|)(C)H-CH_(3))`
(ii) Since `CH_(3)MgCl` is obtained by the action of Mg metal on COMPOUND (B), therefore, (B) must be methyl chloride, `CH_(3)Cl`
`underset("Methyl chloride (B)")(CH_(3)Cl) + Mg overset("Ether")to underset("Methylmag. chloride (C)")(CH_(3)MgCl)`
(iii) Since `CH_(3)Cl` is formed by the action of `PCl_(5)` on compound (A), therefore, compound (A) must be methanol, `CH_(3)OH`.
`underset("Methanol (A)")(CH_(3)OH)+PCl_(5)to underset("Methyl chloride (B)")(CH_(3)Cl)+POCl_(3)+HCl`


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